Bwahaha!!! I think that was the episode I thought "omg, please somebody launch this beotch into outerspace, kthx"... she was just an absolute pill in Season 1. And you know, it's not that (at least) most of the time she was justified. But she was just such an unrelenting harpy. And at that time, Walt is still just this bumbling, pathetic science teacher, in over his head, trying to cook up some meth to pay for his cancer treatment and leave his family a modest nest egg - $700k and some change was his pie in the sky goal, remember? My, how things changed...
She was everything you said, and also, really fricking annoying.
That scene, IMO, perfectly illustrates how everything about Walt's life before meth was underwhelming and pathetic. I also feel like the dynamic between Skyler and Walt had given her the upperhand because he always seemed to be snivelling and grovelling. I just watched the finale, and there is a scene that looks back on the first season where he and Jesse need to stay in the desert longer to finish a cook. Walt walks away to figure out what hes going to tell Skyler about coming home late, and he just sounds like a nervous subordinate, tryng to fgure out something palatable and pleasing to tell The Boss. Of course, its a stark contrast to the Walt of later seasons.
Skyler was also about 10 years younger and more attractive than Walt, even when adjusting for the age dfference. He always seems simultaneously grateful for her, and tired of the grovelling dynamic between them.
Jesse is probably my favourite character in the series, but I actually don't fault Skyler for this at all. Jesse almost burned down their family home and for all she knew, posed a further threat to herself, Walt and their children. I'd want him dead too.